(p, VE, T) Measurements of mixtures (DBE + alcohol) at temperatures from (293.15 to 353.15) K and at pressures up to 140 MPa
This work reports new experimental density data (960 points) for 1-propanol and for binary mixturesof dibutyl ether + 1-propanol, +2-propanol and +1-hexanol over the full composition range (5 composi-tions; 0.15 ≤ dibutyl ether mole fraction x ≤ 0.85), between 293.15 and 353.15 K (every 20 K), and f...
Gespeichert in:
Veröffentlicht in: | Fluid phase equilibria 2014-01 (363), p.131-148 |
---|---|
Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
Zusammenfassung: | This work reports new experimental density data (960 points) for 1-propanol and for binary mixturesof dibutyl ether + 1-propanol, +2-propanol and +1-hexanol over the full composition range (5 composi-tions; 0.15 ≤ dibutyl ether mole fraction x ≤ 0.85), between 293.15 and 353.15 K (every 20 K), and for 15pressures from 0.1 MPa up to 140 MPa (every 10 MPa).An Anton Paar vibrating tube densimeter, calibrated with an uncertainty of ±0.5 kg m−3was usedto perform these measurements. The experimental density data were fitted with a Tait-like equationwith low standard deviations. Excess volumes have been calculated from the experimental data andfitted by the Redlich-Kister equation. In addition, the isobaric thermal expansivity and the isothermalcompressibility have been derived from the Tait-like equation. |
---|---|
ISSN: | 0378-3812 |
DOI: | 10.1016/j.fluid.2013.11.031 |