A novel, efficient synthesis of N-aryl pyrroles via reaction of 1-boronodienes with arylnitroso compounds

A novel, efficient synthesis of N-aryl pyrroles via reaction of 1-boronodienes with arylnitroso compounds

A one-pot hetero-Diels-Alder/ring contraction cascade is presented from the reaction of 1-boronodienes and arylnitroso derivatives to derive N-arylpyrroles in moderate to good yields (up to 82%).

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2013-06, Vol.49 (47), p.5414-5416
Hauptverfasser: Tripoteau, Fabien, Eberlin, Ludovic, Fox, Mark A, Carboni, Bertrand, Whiting, Andrew
Format: Artikel
Sprache:eng
Schlagworte:
Boron Compounds - chemistry
Chemical Sciences
Cycloaddition Reaction
Nitroso Compounds - chemistry
Organic chemistry
Pyrroles - chemical synthesis
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Beschreibung
Zusammenfassung:A one-pot hetero-Diels-Alder/ring contraction cascade is presented from the reaction of 1-boronodienes and arylnitroso derivatives to derive N-arylpyrroles in moderate to good yields (up to 82%).
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc42227e