Magnetic properties of structurally characterized binuclear lanthanide complexes bridged by 2,2′-bipyrimidine

Magnetic coupling in the second half of the lanthanide series through 2,2′-bipyrimidine. A family of five homobimetallic complexes with magnetically-active trivalent lanthanides of the second half of the series with general formula [{Ln(tta)3}2(μ-bpm)] (Ln=Gd, Tb, Dy, Ho, Er, tta=2-thenoyltrifluoroa...

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Veröffentlicht in:Polyhedron 2013-03, Vol.52, p.1262-1267
Hauptverfasser: Zucchi, Gaël, Le Goff, Xavier F.
Format: Artikel
Sprache:eng
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Zusammenfassung:Magnetic coupling in the second half of the lanthanide series through 2,2′-bipyrimidine. A family of five homobimetallic complexes with magnetically-active trivalent lanthanides of the second half of the series with general formula [{Ln(tta)3}2(μ-bpm)] (Ln=Gd, Tb, Dy, Ho, Er, tta=2-thenoyltrifluoroacetonato, bpm=2,2′-bipyrimidine) has been structurally characterized by X-ray diffraction and the magnetic properties of these complexes are reported. The two lanthanide ions are coordinated to the bridging bpm ligand which connects the two metallic centers. The magnetic behavior of these complexes has been investigated. It revealed that a weak antiferromagnetic coupling is observed with the TbIII, DyIII, HoIII, and ErIII ions while a very weak ferromagnetic exchange between the two GdIII ions was observed.
ISSN:0277-5387
0277-5387
DOI:10.1016/j.poly.2012.06.021