MOF-Supported Selective Ethylene Dimerization Single-Site Catalysts through One-Pot Postsynthetic Modification

MOF-Supported Selective Ethylene Dimerization Single-Site Catalysts through One-Pot Postsynthetic Modification

The one-pot postfunctionalization allows anchoring a molecular nickel complex into a mesoporous metal–organic framework (Ni@(Fe)MIL-101). It is generating a very active and reusable catalyst for the liquid-phase ethylene dimerization to selectively form 1-butene. Higher selectivity for 1-butene is f...

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Veröffentlicht in:Journal of the American Chemical Society 2013-03, Vol.135 (11), p.4195-4198
Hauptverfasser: Canivet, Jerome, Aguado, Sonia, Schuurman, Yves, Farrusseng, David
Format: Artikel
Sprache:eng
Schlagworte:
Catalysis
Chemical Sciences
Organic chemistry
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Zusammenfassung:The one-pot postfunctionalization allows anchoring a molecular nickel complex into a mesoporous metal–organic framework (Ni@(Fe)MIL-101). It is generating a very active and reusable catalyst for the liquid-phase ethylene dimerization to selectively form 1-butene. Higher selectivity for 1-butene is found using the Ni@(Fe)MIL-101 catalyst than reported for molecular nickel diimino complexes.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja312120x