Ruthenium( ii )-catalyzed selective monoarylation in water and sequential functionalisations of C–H bonds

Ruthenium( ii )-catalyzed selective monoarylation in water and sequential functionalisations of C–H bonds

The ruthenium(ii)-phosphine catalyst RuCl sub(2)(PPh sub(3))(p -cymene) operating water selectively leads to orthomonoarylation, with arylchlorides and heteroarylhalides, of functional arenes. Further catalytic heteroarylation with Ru(OAc) sub(2)(p-cymene) in water produces mixed bifunctional deriva...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Green chemistry : an international journal and green chemistry resource : GC 2013-01, Vol.15 (1), p.67-71
Hauptverfasser: Arockiam, Percia B, Fischmeister, Cedric, Bruneau, Christian, Dixneuf, Pierre H
Format: Artikel
Sprache:eng
Schlagworte:
Catalysis
Catalysts
Chemical Sciences
Derivatives
Other
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The ruthenium(ii)-phosphine catalyst RuCl sub(2)(PPh sub(3))(p -cymene) operating water selectively leads to orthomonoarylation, with arylchlorides and heteroarylhalides, of functional arenes. Further catalytic heteroarylation with Ru(OAc) sub(2)(p-cymene) in water produces mixed bifunctional derivatives.
ISSN:1463-9262
1463-9270
DOI:10.1039/c2gc36222h