Lewis acid-catalyzed oxidation of benzylamines to benzamides

Lewis acid-catalyzed oxidation of benzylamines to benzamides

A novel Lewis acid-catalyzed oxidation of benzylamines to the corresponding amides has been developed. Using 10 mol% of ZnBr(2) or FeCl(3) as the catalyst and TBHP as the oxidant, amides were produced under mild conditions.

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Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2012-12, Vol.48 (100), p.12237-12239
Hauptverfasser: Wu, Xiao-Feng, Bheeter, Charles Beromeo, Neumann, Helfried, Dixneuf, Pierre H, Beller, Matthias
Format: Artikel
Sprache:eng
Schlagworte:
Amides
Benzamide
Catalysis
Catalysts
Chemical Sciences
Oxidants
Oxidation
Oxidizing agents
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Beschreibung
Zusammenfassung:A novel Lewis acid-catalyzed oxidation of benzylamines to the corresponding amides has been developed. Using 10 mol% of ZnBr(2) or FeCl(3) as the catalyst and TBHP as the oxidant, amides were produced under mild conditions.
ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc37149a