A straightforward access to photochromic diarylethene derivatives via palladium-catalysed direct heteroarylation of 1,2-dichloroperfluorocyclopentene
A novel and efficient palladium-catalysed direct di-heteroarylation of 1,2-dichloroperfluorocyclopentene with a variety of heteroarenes is reported, giving rise to 1,2-di(heteroaryl)ylperfluorocyclopentene photochromic compounds. The reaction proceeds with thiazoles, thiophenes or furan derivatives...
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Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2012-12, Vol.48 (98), p.11951-11953 |
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container_title | Chemical communications (Cambridge, England) |
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creator | Beydoun, Kassem Roger, Julien Boixel, Julien Le Bozec, Hubert Guerchais, Véronique Doucet, Henri |
description | A novel and efficient palladium-catalysed direct di-heteroarylation of 1,2-dichloroperfluorocyclopentene with a variety of heteroarenes is reported, giving rise to 1,2-di(heteroaryl)ylperfluorocyclopentene photochromic compounds. The reaction proceeds with thiazoles, thiophenes or furan derivatives and tolerates various substituents. |
doi_str_mv | 10.1039/c2cc37046h |
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source | MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
subjects | Catalysis Chemical Sciences Cyclopentanes - chemical synthesis Cyclopentanes - chemistry Fluorocarbons - chemical synthesis Fluorocarbons - chemistry Molecular Structure Organometallic Compounds - chemistry Palladium - chemistry Photochemical Processes |
title | A straightforward access to photochromic diarylethene derivatives via palladium-catalysed direct heteroarylation of 1,2-dichloroperfluorocyclopentene |
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