A straightforward access to photochromic diarylethene derivatives via palladium-catalysed direct heteroarylation of 1,2-dichloroperfluorocyclopentene

A novel and efficient palladium-catalysed direct di-heteroarylation of 1,2-dichloroperfluorocyclopentene with a variety of heteroarenes is reported, giving rise to 1,2-di(heteroaryl)ylperfluorocyclopentene photochromic compounds. The reaction proceeds with thiazoles, thiophenes or furan derivatives...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2012-12, Vol.48 (98), p.11951-11953
Hauptverfasser: Beydoun, Kassem, Roger, Julien, Boixel, Julien, Le Bozec, Hubert, Guerchais, Véronique, Doucet, Henri
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container_end_page 11953
container_issue 98
container_start_page 11951
container_title Chemical communications (Cambridge, England)
container_volume 48
creator Beydoun, Kassem
Roger, Julien
Boixel, Julien
Le Bozec, Hubert
Guerchais, Véronique
Doucet, Henri
description A novel and efficient palladium-catalysed direct di-heteroarylation of 1,2-dichloroperfluorocyclopentene with a variety of heteroarenes is reported, giving rise to 1,2-di(heteroaryl)ylperfluorocyclopentene photochromic compounds. The reaction proceeds with thiazoles, thiophenes or furan derivatives and tolerates various substituents.
doi_str_mv 10.1039/c2cc37046h
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ispartof Chemical communications (Cambridge, England), 2012-12, Vol.48 (98), p.11951-11953
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source MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Catalysis
Chemical Sciences
Cyclopentanes - chemical synthesis
Cyclopentanes - chemistry
Fluorocarbons - chemical synthesis
Fluorocarbons - chemistry
Molecular Structure
Organometallic Compounds - chemistry
Palladium - chemistry
Photochemical Processes
title A straightforward access to photochromic diarylethene derivatives via palladium-catalysed direct heteroarylation of 1,2-dichloroperfluorocyclopentene
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