A straightforward access to photochromic diarylethene derivatives via palladium-catalysed direct heteroarylation of 1,2-dichloroperfluorocyclopentene

A straightforward access to photochromic diarylethene derivatives via palladium-catalysed direct heteroarylation of 1,2-dichloroperfluorocyclopentene

A novel and efficient palladium-catalysed direct di-heteroarylation of 1,2-dichloroperfluorocyclopentene with a variety of heteroarenes is reported, giving rise to 1,2-di(heteroaryl)ylperfluorocyclopentene photochromic compounds. The reaction proceeds with thiazoles, thiophenes or furan derivatives...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2012-12, Vol.48 (98), p.11951-11953
Hauptverfasser: Beydoun, Kassem, Roger, Julien, Boixel, Julien, Le Bozec, Hubert, Guerchais, Véronique, Doucet, Henri
Format: Artikel
Sprache:eng
Schlagworte:
Catalysis
Chemical Sciences
Cyclopentanes - chemical synthesis
Cyclopentanes - chemistry
Fluorocarbons - chemical synthesis
Fluorocarbons - chemistry
Molecular Structure
Organometallic Compounds - chemistry
Palladium - chemistry
Photochemical Processes
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:A novel and efficient palladium-catalysed direct di-heteroarylation of 1,2-dichloroperfluorocyclopentene with a variety of heteroarenes is reported, giving rise to 1,2-di(heteroaryl)ylperfluorocyclopentene photochromic compounds. The reaction proceeds with thiazoles, thiophenes or furan derivatives and tolerates various substituents.
ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc37046h