An Electron-Conducting Cross-Linked Polyaniline-Based Redox Hydrogel, Formed in One Step at pH 7.2, Wires Glucose Oxidase
A polyaniline-based, electron-conducting, glucose-permeable, redox hydrogel was formed in one step at pH 7.2 by cross-linking polymer acid-templated polyaniline with a water-soluble diepoxide, poly(ethylene glycol diglycidyl ether). Coimmobilization of glucose oxidase in the hydrogel, by co-cross-li...
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Veröffentlicht in: | Journal of the American Chemical Society 2007-06, Vol.129 (22), p.7006-7007 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | A polyaniline-based, electron-conducting, glucose-permeable, redox hydrogel was formed in one step at pH 7.2 by cross-linking polymer acid-templated polyaniline with a water-soluble diepoxide, poly(ethylene glycol diglycidyl ether). Coimmobilization of glucose oxidase in the hydrogel, by co-cross-linking in the same step, led to the electrical wiring of the enzyme and to the formation of a glucose electrooxidation catalyst, allowing the electrocatalytic oxidation of glucose at a steady-state current density of 225 μA·cm-2 at 0.3 V vs Ag/AgCl. |
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ISSN: | 0002-7863 1520-5126 |
DOI: | 10.1021/ja071946c |