(Eta6-arene) ruthenium(II) complexes and metallo-papain hybrid as Lewis acid catalysts of Diels-Alder reaction in water
Covalent embedding of a (eta(6)-arene) ruthenium(II) complex into the protein papain gives rise to a metalloenzyme displaying a catalytic efficiency for a Lewis acid-mediated catalysed Diels-Alder reaction enhanced by two orders of magnitude in water.
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2010, Vol.39 (24), p.5605-5607 |
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| container_end_page | 5607 |
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| container_issue | 24 |
| container_start_page | 5605 |
| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 39 |
| creator | Talbi, Barisa Haquette, Pierre Martel, Annie de Montigny, Frédéric Fosse, Céline Cordier, Stéphane Roisnel, Thierry Jaouen, Gérard Salmain, Michèle |
| description | Covalent embedding of a (eta(6)-arene) ruthenium(II) complex into the protein papain gives rise to a metalloenzyme displaying a catalytic efficiency for a Lewis acid-mediated catalysed Diels-Alder reaction enhanced by two orders of magnitude in water. |
| doi_str_mv | 10.1039/c001630f |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2010, Vol.39 (24), p.5605-5607 |
| issn | 1477-9226 1477-9234 |
| language | eng |
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| source | MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Acids - chemistry Catalysis Catalysts Chemical Sciences Coordination chemistry Coordination Complexes - chemistry Covalence Crystallography, X-Ray Diels-Alder reactions Kinetics Lewis acid Molecular Conformation Papain Papain - chemistry Prints Proteins Ruthenium - chemistry Water - chemistry |
| title | (Eta6-arene) ruthenium(II) complexes and metallo-papain hybrid as Lewis acid catalysts of Diels-Alder reaction in water |
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