(Eta6-arene) ruthenium(II) complexes and metallo-papain hybrid as Lewis acid catalysts of Diels-Alder reaction in water

Covalent embedding of a (eta(6)-arene) ruthenium(II) complex into the protein papain gives rise to a metalloenzyme displaying a catalytic efficiency for a Lewis acid-mediated catalysed Diels-Alder reaction enhanced by two orders of magnitude in water.

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Bibliographische Detailangaben
Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2010, Vol.39 (24), p.5605-5607
Hauptverfasser:	Talbi, Barisa, Haquette, Pierre, Martel, Annie, de Montigny, Frédéric, Fosse, Céline, Cordier, Stéphane, Roisnel, Thierry, Jaouen, Gérard, Salmain, Michèle
Format:	Artikel
Sprache:	eng
Schlagworte:	Acids - chemistry Catalysis Catalysts Chemical Sciences Coordination chemistry Coordination Complexes - chemistry Covalence Crystallography, X-Ray Diels-Alder reactions Kinetics Lewis acid Molecular Conformation Papain Papain - chemistry Prints Proteins Ruthenium - chemistry Water - chemistry
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Beschreibung
Zusammenfassung:	Covalent embedding of a (eta(6)-arene) ruthenium(II) complex into the protein papain gives rise to a metalloenzyme displaying a catalytic efficiency for a Lewis acid-mediated catalysed Diels-Alder reaction enhanced by two orders of magnitude in water.
ISSN:	1477-9226 1477-9234
DOI:	10.1039/c001630f