Cu-mediated solid-state reaction in a post-functionalized metal–organic framework

Cu-mediated solid-state reaction in a post-functionalized metal–organic framework

We serendipitously found that a functionalized MOF containing grafted copper species can react with itself without solvent in order to modify the chemical functions present on its walls. The use of EPR techniques allows new insight into the copper-mediated azide reduction.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:CrystEngComm 2012-01, Vol.14 (12), p.4105-4108
Hauptverfasser: Savonnet, Marie, Canivet, Jérôme, Gambarelli, Serge, Dubois, Lionel, Bazer-Bachi, Delphine, Lecocq, Vincent, Bats, Nicolas, Farrusseng, David
Format: Artikel
Sprache:eng
Schlagworte:
Catalysis
Chemical Sciences
Copper
Environment and Society
Environmental Sciences
Grafting
Metal-organic frameworks
Reduction
Solvents
Walls
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:We serendipitously found that a functionalized MOF containing grafted copper species can react with itself without solvent in order to modify the chemical functions present on its walls. The use of EPR techniques allows new insight into the copper-mediated azide reduction.
ISSN:1466-8033
1466-8033
DOI:10.1039/c2ce00017b