Synthesis of chiral thiazoline ligands tethered to a sulfur function and first immobilization of a thiazoline-ligand

Synthesis of chiral thiazoline ligands tethered to a sulfur function and first immobilization of a thiazoline-ligand

A new family of thiazoline ligands tethered to a sulfanyl or a sulfinyl group has been prepared using short and efficient reaction sequences. Among the different structures, one sulfanyl‐thiazoline homopolymer was synthesized as a first example of an immobilized thiazoline ligand. The catalytic prop...

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Veröffentlicht in:Heteroatom chemistry 2010, Vol.21 (4), p.242-249
Hauptverfasser: Abrunhosa-Thomas, Isabelle, Betz, Alexander, Denancé, Mickael, Dez, Isabelle, Gaumont, Annie-Claude, Gulea, Mihaela
Format: Artikel
Sprache:eng
Schlagworte:
Chemical Sciences
Organic chemistry
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Zusammenfassung:A new family of thiazoline ligands tethered to a sulfanyl or a sulfinyl group has been prepared using short and efficient reaction sequences. Among the different structures, one sulfanyl‐thiazoline homopolymer was synthesized as a first example of an immobilized thiazoline ligand. The catalytic properties of these new ligands were evaluated in the Pd‐catalyzed allylic substitution. © 2010 Wiley Periodicals, Inc. Heteroatom Chem 21:242–249, 2010; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20603
ISSN:1042-7163
1098-1071
DOI:10.1002/hc.20603