Tailoring metal-organic framework catalysts by click chemistry

Tailoring metal-organic framework catalysts by click chemistry

We successively introduce new catalytic centers through click reaction into MOFs and modify their environment by addition of lipophilic groups. The resulting bifunctionalized MOF provides an optimized balance between basicity and lipophilicity and shows outstanding performance for the transesterific...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2012-04, Vol.41 (14), p.3945-3948
Hauptverfasser: Savonnet, Marie, Camarata, Aurélie, Canivet, Jerome, Bazer-Bachi, Delphine, Bats, Nicolas, Lecocq, Vincent, Pinel, Catherine, Farrusseng, David
Format: Artikel
Sprache:eng
Schlagworte:
Basicity
Catalysis
Catalysts
Chemical Sciences
Environment and Society
Environmental Sciences
Lipophilicity
Metal-organic frameworks
Transesterification
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Beschreibung
Zusammenfassung:We successively introduce new catalytic centers through click reaction into MOFs and modify their environment by addition of lipophilic groups. The resulting bifunctionalized MOF provides an optimized balance between basicity and lipophilicity and shows outstanding performance for the transesterification reaction.
ISSN:1477-9226
1477-9234
DOI:10.1039/c2dt11994c