Diastereo- and Enantioselective Intramolecular C(sp3)H Arylation for the Synthesis of Fused Cyclopentanes
All CH bonds are not equal: The intramolecular arylation of unactivated C(sp3)H bonds in the presence of a chiral Pd/binepine catalyst allows the synthesis of fused cyclopentanes efficiently and in an diastereo‐ and enantioselective manner (see scheme).
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| Veröffentlicht in: | Chemistry : a European journal 2012-04, Vol.18 (15), p.4480-4484 |
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| container_end_page | 4484 |
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| container_issue | 15 |
| container_start_page | 4480 |
| container_title | Chemistry : a European journal |
| container_volume | 18 |
| creator | Martin, Nicolas Pierre, Cathleen Davi, Michaël Jazzar, Rodolphe Baudoin, Olivier |
| description | All CH bonds are not equal: The intramolecular arylation of unactivated C(sp3)H bonds in the presence of a chiral Pd/binepine catalyst allows the synthesis of fused cyclopentanes efficiently and in an diastereo‐ and enantioselective manner (see scheme). |
| doi_str_mv | 10.1002/chem.201200018 |
| format | Article |
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| identifier | ISSN: 0947-6539 |
| ispartof | Chemistry : a European journal, 2012-04, Vol.18 (15), p.4480-4484 |
| issn | 0947-6539 1521-3765 |
| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | asymmetric catalysis Catalysts Chemical Sciences Chemistry CC coupling CH activation Organic chemistry Palladium Synthesis |
| title | Diastereo- and Enantioselective Intramolecular C(sp3)H Arylation for the Synthesis of Fused Cyclopentanes |
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