Zinc-Adeninate Metal−Organic Framework for Aqueous Encapsulation and Sensitization of Near-infrared and Visible Emitting Lanthanide Cations

Zinc-Adeninate Metal−Organic Framework for Aqueous Encapsulation and Sensitization of Near-infrared and Visible Emitting Lanthanide Cations

Luminescent metal−organic frameworks (MOFs), Ln 3+ @bio-MOF-1, were synthesized via postsynthetic cation exchange of bio-MOF-1 with Tb3+, Sm3+, Eu3+, or Yb3+, and their photophysical properties were studied. We demonstrate that bio-MOF-1 encapsulates and sensitizes visible and near-infrared emitting...

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Veröffentlicht in:Journal of the American Chemical Society 2011-02, Vol.133 (5), p.1220-1223
Hauptverfasser: An, Jihyun, Shade, Chad M, Chengelis-Czegan, Demetra A, Petoud, Stéphane, Rosi, Nathaniel L
Format: Artikel
Sprache:eng
Schlagworte:
Adenine - chemistry
Chemical Sciences
Infrared Rays
Lanthanoid Series Elements - chemistry
Luminescent Agents - chemistry
Luminescent Measurements
Organometallic Compounds - chemistry
Solutions
Water - chemistry
Zinc - chemistry
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Zusammenfassung:Luminescent metal−organic frameworks (MOFs), Ln 3+ @bio-MOF-1, were synthesized via postsynthetic cation exchange of bio-MOF-1 with Tb3+, Sm3+, Eu3+, or Yb3+, and their photophysical properties were studied. We demonstrate that bio-MOF-1 encapsulates and sensitizes visible and near-infrared emitting lanthanide cations in aqueous solution.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja109103t