Breathing Transitions in MIL-53(Al) Metal-Organic Framework Upon Xenon Adsorption

Breathing Transitions in MIL-53(Al) Metal-Organic Framework Upon Xenon Adsorption

MOFs come alive: The combination of gas‐adsorption experiments at various temperatures with an osmotic thermodynamic model produced a generic temperature–loading phase diagram that displays unexpected re‐entrant behavior. The breathing effect in the metal–organic framework MIL‐53(Al) is predicted to...

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Veröffentlicht in:Angewandte Chemie (International ed.) 2009-10, Vol.48 (44), p.8314-8317
Hauptverfasser: Boutin, Anne, Springuel-Huet, Marie-Anne, Nossov, Andrei, Gédéon, Antoine, Loiseau, Thierry, Volkringer, Christophe, Férey, Gérard, Coudert, François-Xavier, Fuchs, Alain H
Format: Artikel
Sprache:eng
Schlagworte:
adsorption
Chemical Sciences
Material chemistry
metal-organic frameworks
nanoporous materials
or physical chemistry
Theoretical and
thermodynamics
xenon
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Zusammenfassung:MOFs come alive: The combination of gas‐adsorption experiments at various temperatures with an osmotic thermodynamic model produced a generic temperature–loading phase diagram that displays unexpected re‐entrant behavior. The breathing effect in the metal–organic framework MIL‐53(Al) is predicted to be general and should be observed over a limited temperature range regardless of the guest adsorbate.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200903153