A Model study for Diels–Alder reaction of biscyclopentadienyl monomer with bismaleimides. Benzylcyclopentadiene: synthesis, characterization and Diels–Alder reaction with N-(4-benzoyl)-phenylmaleimide

A Model study for Diels–Alder reaction of biscyclopentadienyl monomer with bismaleimides. Benzylcyclopentadiene: synthesis, characterization and Diels–Alder reaction with N-(4-benzoyl)-phenylmaleimide

Reaction between benzylbromide and sodium cyclopentadienide leads to a mixture of dienes. These can be identified by several techniques such as size exclusion chromatography, mass spectroscopy (MS) and high performance liquid chromatography/MS coupling. Their structure is confirmed by analysis of ad...

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Veröffentlicht in:Polymer (Guilford) 2000-02, Vol.41 (4), p.1633-1639
Hauptverfasser: Romdhane, H.Ben, Chaâbouni, M.R., Grenier-Loustalot, M.F., Delolme, F., Mison, P., Sillion, B.
Format: Artikel
Sprache:eng
Schlagworte:
Analytical chemistry
Applied sciences
Chemical properties
Chemical Sciences
Cyclopentadiene
Diels–Alder
Exact sciences and technology
Maleimide
Polymer industry, paints, wood
Properties and testing
Technology of polymers
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Zusammenfassung:Reaction between benzylbromide and sodium cyclopentadienide leads to a mixture of dienes. These can be identified by several techniques such as size exclusion chromatography, mass spectroscopy (MS) and high performance liquid chromatography/MS coupling. Their structure is confirmed by analysis of adducts obtained after reaction of N-(4-benzoyl)-phenylmaleimide with these dienes.
ISSN:0032-3861
1873-2291
DOI:10.1016/S0032-3861(99)00391-2