Solid state chemistry for connecting the pieces of the high-TC superconducting puzzle?

In high-TC cuprates, superposition to a localized low-energy antiferromagnetic background of a delocalized high-energy assembly of exciton-solvated doping holes (ESH) accounts for singlet state hole pairing in real space, above TC. Below TC, pairs can glide in coherent motion along one-dimensional s...

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Veröffentlicht in:Solid state sciences 2010, Vol.12 (5), p.691-698
Hauptverfasser: Pouchard, Michel, Doumerc, Jean-Pierre, Villesuzanne, Antoine
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Sprache:eng
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Zusammenfassung:In high-TC cuprates, superposition to a localized low-energy antiferromagnetic background of a delocalized high-energy assembly of exciton-solvated doping holes (ESH) accounts for singlet state hole pairing in real space, above TC. Below TC, pairs can glide in coherent motion along one-dimensional spines, formed by aligned charge transfer excitons, and serving as rails. Most of old and new experimental observations agree with this model. In high-TC cuprates, Coulomb interactions between exciton-solvated doping holes (ESH) can result in real-space pairing of holes.
ISSN:1293-2558
DOI:10.1016/j.solidstatesciences.2009.06.004