Gas-Phase Hydrogenation of Propionitrile Catalyzed by LnCu2 (Ln = La, Ce, Pr, Nd)

Gas-Phase Hydrogenation of Propionitrile Catalyzed by LnCu2 (Ln = La, Ce, Pr, Nd)

The hydrogenation of propionitrile over binary copper−lanthanide intermetallic compounds (LnCu2, Ln = La, Ce, Pr, Nd) was studied in the gas phase. The results show that the reaction main product is the primary amine, the n-propylamine. To our knowledge, it is the first time that such behavior is re...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of physical chemistry. C 2007-10, Vol.111 (41), p.15084-15088
Hauptverfasser: Branco, Joaquim Badalo, Ballivet-Tkatchenko, Danielle, Pires de Matos, António
Format: Artikel
Sprache:eng
Schlagworte:
Catalysis
Chemical Sciences
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 15088
container_issue 41
container_start_page 15084
container_title Journal of physical chemistry. C
container_volume 111
creator Branco, Joaquim Badalo
Ballivet-Tkatchenko, Danielle
Pires de Matos, António
description The hydrogenation of propionitrile over binary copper−lanthanide intermetallic compounds (LnCu2, Ln = La, Ce, Pr, Nd) was studied in the gas phase. The results show that the reaction main product is the primary amine, the n-propylamine. To our knowledge, it is the first time that such behavior is reported for copper catalysts.
doi_str_mv 10.1021/jp074369n
format Article
fullrecord <record><control><sourceid>acs_hal_p</sourceid><recordid>TN_cdi_hal_primary_oai_HAL_hal_00469878v1</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>i96687974</sourcerecordid><originalsourceid>FETCH-LOGICAL-a172t-3fee63cd88e72c122e3d257d6efaa472e872364c99478b1de9b2804d58d490c83</originalsourceid><addsrcrecordid>eNo90E1Lw0AQBuBFFKzVg_9gL4KFRvcr2d2DhxK0EYK2GM_LNLuxqTEp2VSMv96USk_zMjwMzIvQNSV3lDB6v9kSKXik6xM0opqzQIowPD1mIc_RhfcbQkJOKB-h5Rx8sFiDdzjpbdt8uBq6sqlxU-BF22yHWHZtWTkcQwdV_-ssXvU4reMdw7dpjR9wClMcu-nAp_jFTi7RWQGVd1f_c4zenx6zOAnS1_lzPEsDoJJ1AS-ci3hulXKS5ZQxxy0LpY1cASAkc0oyHolcayHVilqnV0wRYUNlhSa54mM0OdxdQ2W2bfkFbW8aKE0yS81-R4iItJLqmw42ONjSd-7nqKH9NJHkMjTZ4s0kLM2WIgtNPPibg4fcm02za-vhE0OJ2Xdsjh3zP-i6ahk</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Gas-Phase Hydrogenation of Propionitrile Catalyzed by LnCu2 (Ln = La, Ce, Pr, Nd)</title><source>American Chemical Society</source><creator>Branco, Joaquim Badalo ; Ballivet-Tkatchenko, Danielle ; Pires de Matos, António</creator><creatorcontrib>Branco, Joaquim Badalo ; Ballivet-Tkatchenko, Danielle ; Pires de Matos, António</creatorcontrib><description>The hydrogenation of propionitrile over binary copper−lanthanide intermetallic compounds (LnCu2, Ln = La, Ce, Pr, Nd) was studied in the gas phase. The results show that the reaction main product is the primary amine, the n-propylamine. To our knowledge, it is the first time that such behavior is reported for copper catalysts.</description><identifier>ISSN: 1932-7447</identifier><identifier>EISSN: 1932-7455</identifier><identifier>DOI: 10.1021/jp074369n</identifier><language>eng</language><publisher>American Chemical Society</publisher><subject>Catalysis ; Chemical Sciences</subject><ispartof>Journal of physical chemistry. C, 2007-10, Vol.111 (41), p.15084-15088</ispartof><rights>Copyright © 2007 American Chemical Society</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/jp074369n$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/jp074369n$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>230,314,780,784,885,27076,27924,27925,56738,56788</link.rule.ids><backlink>$$Uhttps://hal.science/hal-00469878$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Branco, Joaquim Badalo</creatorcontrib><creatorcontrib>Ballivet-Tkatchenko, Danielle</creatorcontrib><creatorcontrib>Pires de Matos, António</creatorcontrib><title>Gas-Phase Hydrogenation of Propionitrile Catalyzed by LnCu2 (Ln = La, Ce, Pr, Nd)</title><title>Journal of physical chemistry. C</title><addtitle>J. Phys. Chem. C</addtitle><description>The hydrogenation of propionitrile over binary copper−lanthanide intermetallic compounds (LnCu2, Ln = La, Ce, Pr, Nd) was studied in the gas phase. The results show that the reaction main product is the primary amine, the n-propylamine. To our knowledge, it is the first time that such behavior is reported for copper catalysts.</description><subject>Catalysis</subject><subject>Chemical Sciences</subject><issn>1932-7447</issn><issn>1932-7455</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><recordid>eNo90E1Lw0AQBuBFFKzVg_9gL4KFRvcr2d2DhxK0EYK2GM_LNLuxqTEp2VSMv96USk_zMjwMzIvQNSV3lDB6v9kSKXik6xM0opqzQIowPD1mIc_RhfcbQkJOKB-h5Rx8sFiDdzjpbdt8uBq6sqlxU-BF22yHWHZtWTkcQwdV_-ssXvU4reMdw7dpjR9wClMcu-nAp_jFTi7RWQGVd1f_c4zenx6zOAnS1_lzPEsDoJJ1AS-ci3hulXKS5ZQxxy0LpY1cASAkc0oyHolcayHVilqnV0wRYUNlhSa54mM0OdxdQ2W2bfkFbW8aKE0yS81-R4iItJLqmw42ONjSd-7nqKH9NJHkMjTZ4s0kLM2WIgtNPPibg4fcm02za-vhE0OJ2Xdsjh3zP-i6ahk</recordid><startdate>20071018</startdate><enddate>20071018</enddate><creator>Branco, Joaquim Badalo</creator><creator>Ballivet-Tkatchenko, Danielle</creator><creator>Pires de Matos, António</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>1XC</scope></search><sort><creationdate>20071018</creationdate><title>Gas-Phase Hydrogenation of Propionitrile Catalyzed by LnCu2 (Ln = La, Ce, Pr, Nd)</title><author>Branco, Joaquim Badalo ; Ballivet-Tkatchenko, Danielle ; Pires de Matos, António</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a172t-3fee63cd88e72c122e3d257d6efaa472e872364c99478b1de9b2804d58d490c83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><topic>Catalysis</topic><topic>Chemical Sciences</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Branco, Joaquim Badalo</creatorcontrib><creatorcontrib>Ballivet-Tkatchenko, Danielle</creatorcontrib><creatorcontrib>Pires de Matos, António</creatorcontrib><collection>Istex</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Journal of physical chemistry. C</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Branco, Joaquim Badalo</au><au>Ballivet-Tkatchenko, Danielle</au><au>Pires de Matos, António</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Gas-Phase Hydrogenation of Propionitrile Catalyzed by LnCu2 (Ln = La, Ce, Pr, Nd)</atitle><jtitle>Journal of physical chemistry. C</jtitle><addtitle>J. Phys. Chem. C</addtitle><date>2007-10-18</date><risdate>2007</risdate><volume>111</volume><issue>41</issue><spage>15084</spage><epage>15088</epage><pages>15084-15088</pages><issn>1932-7447</issn><eissn>1932-7455</eissn><abstract>The hydrogenation of propionitrile over binary copper−lanthanide intermetallic compounds (LnCu2, Ln = La, Ce, Pr, Nd) was studied in the gas phase. The results show that the reaction main product is the primary amine, the n-propylamine. To our knowledge, it is the first time that such behavior is reported for copper catalysts.</abstract><pub>American Chemical Society</pub><doi>10.1021/jp074369n</doi><tpages>5</tpages></addata></record>
fulltext fulltext
identifier ISSN: 1932-7447
ispartof Journal of physical chemistry. C, 2007-10, Vol.111 (41), p.15084-15088
issn 1932-7447
1932-7455
language eng
recordid cdi_hal_primary_oai_HAL_hal_00469878v1
source American Chemical Society
subjects Catalysis
Chemical Sciences
title Gas-Phase Hydrogenation of Propionitrile Catalyzed by LnCu2 (Ln = La, Ce, Pr, Nd)
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-25T06%3A21%3A43IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-acs_hal_p&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Gas-Phase%20Hydrogenation%20of%20Propionitrile%20Catalyzed%20by%20LnCu2%20(Ln%20=%20La,%20Ce,%20Pr,%20Nd)&rft.jtitle=Journal%20of%20physical%20chemistry.%20C&rft.au=Branco,%20Joaquim%20Badalo&rft.date=2007-10-18&rft.volume=111&rft.issue=41&rft.spage=15084&rft.epage=15088&rft.pages=15084-15088&rft.issn=1932-7447&rft.eissn=1932-7455&rft_id=info:doi/10.1021/jp074369n&rft_dat=%3Cacs_hal_p%3Ei96687974%3C/acs_hal_p%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true