Gas-Phase Hydrogenation of Propionitrile Catalyzed by LnCu2 (Ln = La, Ce, Pr, Nd)

Gas-Phase Hydrogenation of Propionitrile Catalyzed by LnCu2 (Ln = La, Ce, Pr, Nd)

The hydrogenation of propionitrile over binary copper−lanthanide intermetallic compounds (LnCu2, Ln = La, Ce, Pr, Nd) was studied in the gas phase. The results show that the reaction main product is the primary amine, the n-propylamine. To our knowledge, it is the first time that such behavior is re...

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Veröffentlicht in:Journal of physical chemistry. C 2007-10, Vol.111 (41), p.15084-15088
Hauptverfasser: Branco, Joaquim Badalo, Ballivet-Tkatchenko, Danielle, Pires de Matos, António
Format: Artikel
Sprache:eng
Schlagworte:
Catalysis
Chemical Sciences
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Zusammenfassung:The hydrogenation of propionitrile over binary copper−lanthanide intermetallic compounds (LnCu2, Ln = La, Ce, Pr, Nd) was studied in the gas phase. The results show that the reaction main product is the primary amine, the n-propylamine. To our knowledge, it is the first time that such behavior is reported for copper catalysts.
ISSN:1932-7447
1932-7455
DOI:10.1021/jp074369n