From inconsistent results to high speed hydrosilylation

From inconsistent results to high speed hydrosilylation

After noting that the presence of dihydrogen, generated in situ from the partial hydrolysis of a silane with residual water, significantly enhances the rate of the rhodium-catalysed hydrosilylation of acetophenone, we developed a high speed hydrosilylation reaction under dihydrogen pressure.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2007-01 (7), p.713-715
Hauptverfasser: Comte, Virginie, Balan, Cédric, Le Gendre, Pierre, Moïse, Claude
Format: Artikel
Sprache:eng
Schlagworte:
Catalysis
Chemical Sciences
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Zusammenfassung:After noting that the presence of dihydrogen, generated in situ from the partial hydrolysis of a silane with residual water, significantly enhances the rate of the rhodium-catalysed hydrosilylation of acetophenone, we developed a high speed hydrosilylation reaction under dihydrogen pressure.
ISSN:1359-7345
1364-548X
DOI:10.1039/b617413b