Heterolytic dihydrogen activation in an iridium complex with a pendant basic group

Heterolytic dihydrogen activation in an iridium complex with a pendant basic group

Experimental and theoretical studies show that H-2 reacts with an Ir phosphine complex having a basic pendant amino group to give either an H-2 or an Lr-H ... H-N hydrogen-bonded hydride complex, depending on the basicity of the phosphine ligands.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 1999-02 (3), p.297-298
Hauptverfasser: Lee, Dong-Heon, Patel, Ben P., Crabtree, Robert H., Clot, Eric, Eisenstein, Odile
Format: Artikel
Sprache:eng
Schlagworte:
Chemical Physics
Physics
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Beschreibung
Zusammenfassung:Experimental and theoretical studies show that H-2 reacts with an Ir phosphine complex having a basic pendant amino group to give either an H-2 or an Lr-H ... H-N hydrogen-bonded hydride complex, depending on the basicity of the phosphine ligands.
ISSN:1359-7345
1364-548X
DOI:10.1039/a808601j