Toward an Easy Access to Dendrimer-like Poly(ethylene oxide)s

Dendrimer-like poly(ethylene oxide)s (PEOs) were synthesized by an iterative divergent approach combining anionic polymerization of ethylene oxide from multi-hydroxylated precursors and branching reactions of PEO chain ends. Partial deprotonation of the hydroxyls (

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Bibliographische Detailangaben
Veröffentlicht in:	Journal of the American Chemical Society 2005-08, Vol.127 (31), p.10956-10966
Hauptverfasser:	Feng, Xiao-Shuang, Taton, Daniel, Chaikof, Elliot L, Gnanou, Yves
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Chemical Sciences Exact sciences and technology Magnetic Resonance Spectroscopy Models, Molecular Organic polymers Physicochemistry of polymers Polyethylene Glycols - chemical synthesis Polyethylene Glycols - chemistry Polymers Polymers with particular structures Preparation, kinetics, thermodynamics, mechanism and catalysts
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Beschreibung
Zusammenfassung:	Dendrimer-like poly(ethylene oxide)s (PEOs) were synthesized by an iterative divergent approach combining anionic polymerization of ethylene oxide from multi-hydroxylated precursors and branching reactions of PEO chain ends. Partial deprotonation of the hydroxyls (
ISSN:	0002-7863 1520-5126
DOI:	10.1021/ja0509432