Ion transport in CLIP: Investigation through conductivity and NMR measurements

The study deals with the electrochemical and physico-chemical characterizations of new proton-conducting ionic liquids. Through the use of several amines and perfluorinated acids, it attempts to define the most appropriate ionic liquids for use in high temperature PEMFCs. In addition to the usual ch...

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Veröffentlicht in:	Electrochimica acta 2007-12, Vol.53 (4), p.1395-1403
Hauptverfasser:	Iojoiu, Cristina, Judeinstein, Patrick, Sanchez, Jean-Yves
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Chemical Sciences CLIP COSY Energy Energy. Thermal use of fuels Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc Exact sciences and technology Fuel cells HOESY Material chemistry NOESY PCIL PEMFC PFG NMR Proton-conducting ionic liquids
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Beschreibung
Zusammenfassung:	The study deals with the electrochemical and physico-chemical characterizations of new proton-conducting ionic liquids. Through the use of several amines and perfluorinated acids, it attempts to define the most appropriate ionic liquids for use in high temperature PEMFCs. In addition to the usual characterizations based on Pulsed Field Gradient NMR and conductivity measurements, NMR correlation techniques NOESY, HOESY and COSY experiments are used to characterize the interactions and spatial proximities of ionic liquid species.
ISSN:	0013-4686 1873-3859
DOI:	10.1016/j.electacta.2007.04.065