Mixed-metal cluster chemistry. 28. Core enlargement of tungsten-iridium clusters with alkynyl, ethynediyl and butadiynediyl reagents

Mixed-metal cluster chemistry. 28. Core enlargement of tungsten-iridium clusters with alkynyl, ethynediyl and butadiynediyl reagents

We report herein studies exploring the utility of selected metal alkynyl, ethyndiyl, and butadiyndiyl complexes in expanding the core nuclearity of tetranuclear tungsten-iridium clusters.

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Veröffentlicht in:Inorganic chemistry 2005-02, Vol.44, p.3261-3269
Hauptverfasser: Dalton, G. T., Viau, Lydie, Watermann, Susan, Humphrey, Mark, Bruce, Michael, Low, Paul, Roberts, Rachelle L., Willis, Anthony C., Koutsantonis, G.A., Skelton, Brian W., White, Allanh H.
Format: Artikel
Sprache:eng
Schlagworte:
Chemical Sciences
Inorganic chemistry
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Zusammenfassung:We report herein studies exploring the utility of selected metal alkynyl, ethyndiyl, and butadiyndiyl complexes in expanding the core nuclearity of tetranuclear tungsten-iridium clusters.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic050040+