Complex Emulsion Inversion Pattern Associated with the Partitioning of Nonionic Surfactant Mixtures in the Presence of Alcohol Cosurfactant

Commercial ethoxylated nonionic surfactant mixtures containing alcohol cosurfactant exhibit a three-phase behavior whose formulation strongly varies with the water/oil ratio. As a consequence, a change in water/oil ratio can result in a sequence of up to three different emulsion inversion processes,...

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Veröffentlicht in:Langmuir 2005-07, Vol.21 (15), p.6712-6716
Hauptverfasser: Marfisi, Shirley, Rodríguez, María Patricia, Alvarez, Gabriela, Celis, María-Teresa, Forgiarini, Ana, Lachaise, Jean, Salager, Jean-Louis
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Sprache:eng
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Zusammenfassung:Commercial ethoxylated nonionic surfactant mixtures containing alcohol cosurfactant exhibit a three-phase behavior whose formulation strongly varies with the water/oil ratio. As a consequence, a change in water/oil ratio can result in a sequence of up to three different emulsion inversion processes, through a combination of formulation and composition effects.
ISSN:0743-7463
1520-5827
DOI:10.1021/la050450a