Butterfly Light Scattering Pattern and Rheology of a Sheared Thixotropic Clay Gel

The behavior of a thixotropic clay gel under shear flow, is studied by combining a static light scattering technique and rheometric measurements. In the rest state, the gel structure is composed of micrometer-sized aggregates associated as a fractal mass. Under steady shear, a butterfly-type light s...

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Veröffentlicht in:Physical review letters 1997-12, Vol.79 (23), p.4689-4692
Hauptverfasser: Pignon, Frédéric, Magnin, Albert, Piau, Jean-Michel
Format: Artikel
Sprache:eng
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Zusammenfassung:The behavior of a thixotropic clay gel under shear flow, is studied by combining a static light scattering technique and rheometric measurements. In the rest state, the gel structure is composed of micrometer-sized aggregates associated as a fractal mass. Under steady shear, a butterfly-type light scattering pattern is observed. This can be related to a contraction and a stretching of the micrometer-sized aggregates, perpendicularly to the shear direction. The influence of the shear rate on the disaggregation process is also studied and correlated to rheometric measurements.
ISSN:0031-9007
1079-7114
DOI:10.1103/PhysRevLett.79.4689