The remarkable effect of the 7-substituent in the diastereoselective oxidative rearrangement of indoles: asymmetric synthesis of 3,3-disubstituted oxindoles

The remarkable effect of the 7-substituent in the diastereoselective oxidative rearrangement of indoles: asymmetric synthesis of 3,3-disubstituted oxindoles

The nature of the 7-substituent has a remarkable effect on the diastereoselectivity of the oxidative rearrangement of indole-2-carboxamides derived from (S)-2-methoxymethylpyrrolidine into chiral 3,3-disubstituted oxindoles.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2007-01 (3), p.286-288
Hauptverfasser: Lachia, Mathilde, Poriel, Cyril, Slawin, Alexandra M Z, Moody, Christopher J
Format: Artikel
Sprache:eng
Schlagworte:
Chemical Physics
Chemical Sciences
Organic chemistry
Physics
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Zusammenfassung:The nature of the 7-substituent has a remarkable effect on the diastereoselectivity of the oxidative rearrangement of indole-2-carboxamides derived from (S)-2-methoxymethylpyrrolidine into chiral 3,3-disubstituted oxindoles.
ISSN:1359-7345
1364-548X
DOI:10.1039/b613716d