Magnetic coupling and long-range order in the spin-chain sulfide Ba2CoS3

In Ba2CoS3, Co2+ cations are in a high spin state and their intra-chain antiferromagnetic coupling constant was calculated. A transition to long-range order was identified to occur at 46 K.

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Bibliographische Detailangaben
Veröffentlicht in:	Journal of materials chemistry 2006-09, Vol.16 (34), p.3489-3502
Hauptverfasser:	BARNES, Andrew D. J, BAIKIE, Thomas, HARDY, Vincent, LEPETIT, Marie-Bernadette, MAIGNAN, Antoine, YOUNG, Nigel A, GRAZIA FRANCESCONI, M
Format:	Artikel
Sprache:	eng
Schlagworte:	Condensed Matter Condensed matter: electronic structure, electrical, magnetic, and optical properties Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Heat capacity Magnetic properties and materials Magnetically ordered materials: other intrinsic properties Physics Saturation moments and magnetic susceptibilities Strongly Correlated Electrons Thermal properties of condensed matter Thermal properties of crystalline solids
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Beschreibung
Zusammenfassung:	In Ba2CoS3, Co2+ cations are in a high spin state and their intra-chain antiferromagnetic coupling constant was calculated. A transition to long-range order was identified to occur at 46 K.
ISSN:	0959-9428 1364-5501
DOI:	10.1039/b605178b