Steric and Electronic Effects Relating to the Cu2+ Jahn−Teller Distortion in Zn1-xCuxAl2O4 Spinels

Steric and Electronic Effects Relating to the Cu2+ Jahn−Teller Distortion in Zn1-xCuxAl2O4 Spinels

Zn1-xCuxAl2O4 (0 < x < 1) compositions have been synthesized by solid-state route, and a color scale going from white (x = 0) to brownish-red (x = 1) with intermediate colors as pale green for x = 0.10 and pale brown for x = 0.30 can be observed...

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Veröffentlicht in:Inorganic chemistry 2007-04, Vol.46 (7), p.2645-2658
Hauptverfasser: LE NESTOUR, A., GAUDON, M., VILLENEUVE, G., ANDRIESSEN, R., DEMOURGUES, A.
Format: Artikel
Sprache:eng
Schlagworte:
Chemical Sciences
Material chemistry
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Zusammenfassung:Zn1-xCuxAl2O4 (0 < x < 1) compositions have been synthesized by solid-state route, and a color scale going from white (x = 0) to brownish-red (x = 1) with intermediate colors as pale green for x = 0.10 and pale brown for x = 0.30 can be observed...
ISSN:0020-1669
1520-510X
DOI:10.1021/ic062329c