Ring opening of 2-phenylazetidines with allylsilanes

Ring opening of 2-phenylazetidines with allylsilanes

N-Activated 2-phenylazetidines were opened regioselectively at the benzylic carbon with various allylsilanes or propargylsilane in the presence of BF 3·Et 2O, providing amino olefins, precursors of biomolecules such as phenyl-homo-kainoids.

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Veröffentlicht in:Tetrahedron letters 2006-03, Vol.47 (13), p.2205-2208
Hauptverfasser: Domostoj, Mathias, Ungureanu, Ioana, Schoenfelder, Angèle, Klotz, Philippe, Mann, André
Format: Artikel
Sprache:eng
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Zusammenfassung:N-Activated 2-phenylazetidines were opened regioselectively at the benzylic carbon with various allylsilanes or propargylsilane in the presence of BF 3·Et 2O, providing amino olefins, precursors of biomolecules such as phenyl-homo-kainoids.
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2006.01.108