Critical behavior of the restricted primitive model revisited

Reassessment of the critical temperature and density of the restricted primitive model of an ionic fluid by Monte Carlo simulations performed for system sizes with linear dimension up to L/σ=34 and sampling of ∼109 trial moves leads to Tc*=0.049 17±0.000 02 and ρc*=0.080±0.005. Finite size scaling a...

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Veröffentlicht in:The Journal of chemical physics 2002-06, Vol.116 (24), p.10794-10800
Hauptverfasser: Caillol, J.-M., Levesque, D., Weis, J.-J.
Format: Artikel
Sprache:eng
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Zusammenfassung:Reassessment of the critical temperature and density of the restricted primitive model of an ionic fluid by Monte Carlo simulations performed for system sizes with linear dimension up to L/σ=34 and sampling of ∼109 trial moves leads to Tc*=0.049 17±0.000 02 and ρc*=0.080±0.005. Finite size scaling analysis based in the Bruce–Wilding procedure gives critical exponents in agreement with those of the three-dimensional Ising universality class. An analysis similar to that proposed by Orkoulas et al. [Phys. Rev. E 63, 051507 (2001)], not relying on an a priori knowledge of the universality class, leads to an inaccurate estimate of Tc* and to unexpected behavior of the specific heat and value of the critical exponent ratio γ/ν.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.1480009