Reactions of (chlorodifluoromethyl)benzene and (chlorodifluoromethoxy)benzene with nucleophilic reagents
Condensation reactions of (chlorodifluoromethyl)benzene and (chlorodifluoromethoxy)benzene with phenoxide and thiophenoxide ions have been performed in DMF or NMP with heating. In these conditions, the reaction between phenylselenide ion and (chlorodifluoromethyl)benzene did not occur. This latter r...
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Veröffentlicht in: | Journal of fluorine chemistry 2005, Vol.126 (4), p.443-447 |
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container_title | Journal of fluorine chemistry |
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creator | Guidotti, Jérôme Schanen, Vincent Tordeux, Marc Wakselman, Claude |
description | Condensation reactions of (chlorodifluoromethyl)benzene and (chlorodifluoromethoxy)benzene with phenoxide and thiophenoxide ions have been performed in DMF or NMP with heating. In these conditions, the reaction between phenylselenide ion and (chlorodifluoromethyl)benzene did not occur. This latter reaction requires an additional visible light irradiation to proceed, as reported by Yoshida et al.
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doi_str_mv | 10.1016/j.jfluchem.2004.10.001 |
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▪</description><subject>Chemical Sciences</subject><subject>Fluoroalkyl halides</subject><subject>Nucleophilic reagents</subject><subject>Organic chemistry</subject><subject>Substitution reaction</subject><issn>0022-1139</issn><issn>1873-3328</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><recordid>eNqFUFFLwzAYDKLgnP4F6aN7aP2SdG365hjqhIEgew9Z-sWmdM1Iu-n89aZM9yT4dHzH3fHdEXJLIaFAs_s6qU2z0xVuEgaQBjIBoGdkREXOY86ZOCcjAMZiSnlxSa66rgaAHHIxItUbKt1b13aRM9GdrhrnXWlDYMAN9tWhmayx_cIWI9WWfync5-Ek-bB9FbU73aDbVraxOvKo3rHtu2tyYVTT4c0Pjsnq6XE1X8TL1-eX-WwZa55mfVwKgVMB2fCvMkaUiBRUmudMC4PTlKWGgTbIw6lVyZXKeVassYSCUaP4mEyOsZVq5NbbjfIH6ZSVi9lSDlxoXqRc8D0N2uyo1d51nUdzMlCQw7Sylr_TymHagQ_TBuPD0YihyN6il5222GosrUfdy9LZ_yK-AX20iQI</recordid><startdate>2005</startdate><enddate>2005</enddate><creator>Guidotti, Jérôme</creator><creator>Schanen, Vincent</creator><creator>Tordeux, Marc</creator><creator>Wakselman, Claude</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>AAYXX</scope><scope>CITATION</scope><scope>1XC</scope></search><sort><creationdate>2005</creationdate><title>Reactions of (chlorodifluoromethyl)benzene and (chlorodifluoromethoxy)benzene with nucleophilic reagents</title><author>Guidotti, Jérôme ; Schanen, Vincent ; Tordeux, Marc ; Wakselman, Claude</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c346t-d88e58060022aff8dee10a4772c8fe5424f20cfe3c8fcad3aa7369bed0921fa3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><topic>Chemical Sciences</topic><topic>Fluoroalkyl halides</topic><topic>Nucleophilic reagents</topic><topic>Organic chemistry</topic><topic>Substitution reaction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Guidotti, Jérôme</creatorcontrib><creatorcontrib>Schanen, Vincent</creatorcontrib><creatorcontrib>Tordeux, Marc</creatorcontrib><creatorcontrib>Wakselman, Claude</creatorcontrib><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Journal of fluorine chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Guidotti, Jérôme</au><au>Schanen, Vincent</au><au>Tordeux, Marc</au><au>Wakselman, Claude</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Reactions of (chlorodifluoromethyl)benzene and (chlorodifluoromethoxy)benzene with nucleophilic reagents</atitle><jtitle>Journal of fluorine chemistry</jtitle><date>2005</date><risdate>2005</risdate><volume>126</volume><issue>4</issue><spage>443</spage><epage>447</epage><pages>443-447</pages><issn>0022-1139</issn><eissn>1873-3328</eissn><abstract>Condensation reactions of (chlorodifluoromethyl)benzene and (chlorodifluoromethoxy)benzene with phenoxide and thiophenoxide ions have been performed in DMF or NMP with heating. In these conditions, the reaction between phenylselenide ion and (chlorodifluoromethyl)benzene did not occur. This latter reaction requires an additional visible light irradiation to proceed, as reported by Yoshida et al.
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subjects | Chemical Sciences Fluoroalkyl halides Nucleophilic reagents Organic chemistry Substitution reaction |
title | Reactions of (chlorodifluoromethyl)benzene and (chlorodifluoromethoxy)benzene with nucleophilic reagents |
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