Reactions of (chlorodifluoromethyl)benzene and (chlorodifluoromethoxy)benzene with nucleophilic reagents

Condensation reactions of (chlorodifluoromethyl)benzene and (chlorodifluoromethoxy)benzene with phenoxide and thiophenoxide ions have been performed in DMF or NMP with heating. In these conditions, the reaction between phenylselenide ion and (chlorodifluoromethyl)benzene did not occur. This latter r...

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Veröffentlicht in:Journal of fluorine chemistry 2005, Vol.126 (4), p.443-447
Hauptverfasser: Guidotti, Jérôme, Schanen, Vincent, Tordeux, Marc, Wakselman, Claude
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container_end_page 447
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container_title Journal of fluorine chemistry
container_volume 126
creator Guidotti, Jérôme
Schanen, Vincent
Tordeux, Marc
Wakselman, Claude
description Condensation reactions of (chlorodifluoromethyl)benzene and (chlorodifluoromethoxy)benzene with phenoxide and thiophenoxide ions have been performed in DMF or NMP with heating. In these conditions, the reaction between phenylselenide ion and (chlorodifluoromethyl)benzene did not occur. This latter reaction requires an additional visible light irradiation to proceed, as reported by Yoshida et al. ▪
doi_str_mv 10.1016/j.jfluchem.2004.10.001
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Fluoroalkyl halides
Nucleophilic reagents
Organic chemistry
Substitution reaction
title Reactions of (chlorodifluoromethyl)benzene and (chlorodifluoromethoxy)benzene with nucleophilic reagents
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