Reactions of (chlorodifluoromethyl)benzene and (chlorodifluoromethoxy)benzene with nucleophilic reagents

Reactions of (chlorodifluoromethyl)benzene and (chlorodifluoromethoxy)benzene with nucleophilic reagents

Condensation reactions of (chlorodifluoromethyl)benzene and (chlorodifluoromethoxy)benzene with phenoxide and thiophenoxide ions have been performed in DMF or NMP with heating. In these conditions, the reaction between phenylselenide ion and (chlorodifluoromethyl)benzene did not occur. This latter r...

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Veröffentlicht in:Journal of fluorine chemistry 2005, Vol.126 (4), p.443-447
Hauptverfasser: Guidotti, Jérôme, Schanen, Vincent, Tordeux, Marc, Wakselman, Claude
Format: Artikel
Sprache:eng
Schlagworte:
Chemical Sciences
Fluoroalkyl halides
Nucleophilic reagents
Organic chemistry
Substitution reaction
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Zusammenfassung:Condensation reactions of (chlorodifluoromethyl)benzene and (chlorodifluoromethoxy)benzene with phenoxide and thiophenoxide ions have been performed in DMF or NMP with heating. In these conditions, the reaction between phenylselenide ion and (chlorodifluoromethyl)benzene did not occur. This latter reaction requires an additional visible light irradiation to proceed, as reported by Yoshida et al. ▪
ISSN:0022-1139
1873-3328
DOI:10.1016/j.jfluchem.2004.10.001