Does Charge Carrier Dimensionality Increase in Mixed-Valence Salts of Tetrathiafulvalene-Terminated Dendrimers?
In four new dendrimers terminated by 12 electroactive tetrathiafulvalenyl substituents, the tridimensional character of the inter- and intradendrimeric charge and electron transfer, and hence of the electroconductivity, is evidenced by examination of the electronic spectra of their corresponding neu...
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Veröffentlicht in: | Organic letters 2004-06, Vol.6 (13), p.2109-2112 |
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Hauptverfasser: | , , , , , , , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | In four new dendrimers terminated by 12 electroactive tetrathiafulvalenyl substituents, the tridimensional character of the inter- and intradendrimeric charge and electron transfer, and hence of the electroconductivity, is evidenced by examination of the electronic spectra of their corresponding neutral state and cation radical, dication, and mixed-valence salts, including a closed-shell anion. |
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ISSN: | 1523-7060 1523-7052 |
DOI: | 10.1021/ol049648x |