In situ evaluation of interfacial affinity in CeO2 based hybrid nanoparticles by pulsed field gradient NMR

Complexation affinity of laurate ligands (C(12)H(23)O(2)) grafted onto the surface of cerium(IV) oxide nanoparticles can be probed and quantified in situ, by pulsed field gradient (1)H NMR through the dependence of the diffusion coefficient on the size of a species.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2005-02, Vol.1 (8), p.1019-1021
Hauptverfasser: Ribot, François, Escax, Virginie, Roiland, Claire, Sanchez, Clément, Martins, José C, Biesemans, Monique, Verbruggen, Ingrid, Willem, Rudolph
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Sprache:eng
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Zusammenfassung:Complexation affinity of laurate ligands (C(12)H(23)O(2)) grafted onto the surface of cerium(IV) oxide nanoparticles can be probed and quantified in situ, by pulsed field gradient (1)H NMR through the dependence of the diffusion coefficient on the size of a species.
ISSN:1359-7345
1364-548X
DOI:10.1039/b411629a