Unusual complexes formed by the early lanthanides with 2,6-bis(5,6-dialkyl-1,2,4-triazin-3-yl)-pyridines

Unusual complexes formed by the early lanthanides with 2,6-bis(5,6-dialkyl-1,2,4-triazin-3-yl)-pyridines

The addition of lanthanide(III) nitrates (La–Sm) to the actinide(III) extracting agents, 2,6-bis(5,6-dialkyl-1,2,4-triazin-3-yl)-pyridines in a 1:1 ratio, results in the crystallisation of unusual dimeric complexes [Ln 2(L 1) 2(NO 3) 6] as well as more usual mononuclear complexes.

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Veröffentlicht in:Inorganic chemistry communications 2001, Vol.4 (9), p.462-466
Hauptverfasser: Drew, Michael G.B., Guillaneux, Denis, Hudson, Michael J., Iveson, Peter B., Madic, Charles
Format: Artikel
Sprache:eng
Schlagworte:
Actinides
Extraction
Lanthanides
Nuclear Experiment
Nuclear reprocessing
Nuclear Theory
Physics
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Zusammenfassung:The addition of lanthanide(III) nitrates (La–Sm) to the actinide(III) extracting agents, 2,6-bis(5,6-dialkyl-1,2,4-triazin-3-yl)-pyridines in a 1:1 ratio, results in the crystallisation of unusual dimeric complexes [Ln 2(L 1) 2(NO 3) 6] as well as more usual mononuclear complexes.
ISSN:1387-7003
1879-0259
DOI:10.1016/S1387-7003(01)00210-6