Covalent Anchoring of Phthalocyanines on Silicon Dioxide Surfaces: Building up Mono- and Multilayers
Ruthenium phthalocyanine (RuPc) monolayers were obtained by self-assembly on pyridino-functionalized metal oxide substrates, by coordination between the ruthenium ions and the pyridino groups. The substrates were functionalized by silanization with a bifunctional silane. Soluble ruthenium phthalocya...
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Veröffentlicht in: | Langmuir 2001-03, Vol.17 (6), p.1928-1935 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Ruthenium phthalocyanine (RuPc) monolayers were obtained by self-assembly on pyridino-functionalized metal oxide substrates, by coordination between the ruthenium ions and the pyridino groups. The substrates were functionalized by silanization with a bifunctional silane. Soluble ruthenium phthalocyanines, axially coordinated by labile benzonitrile groups, were used. A ligand exchange reaction was involved, one benzonitrile group being replaced by pyridine. These RuPc monolayers were characterized by transmission UV−vis spectroscopy, atomic force microscopy, polarization modulation infrared reflection−absorption spectroscopy, and time-of-flight secondary ion mass spectrometry. A second ligand exchange reaction allowed us to build RuPc bilayers by two different strategies. A mixed RuPc/cobalt porphyrin bilayer was also obtained. |
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ISSN: | 0743-7463 1520-5827 |
DOI: | 10.1021/la001237b |