Separation and quantification of polar pesticides in well, surface, and drinking water by capillary electrophoresis

s The optimal conditions for the separation and quantification of pesticides of the following classes by capillary electrophoresis are found: aryloxy carboxylic acids, sym -triazines, triazinones, chloroacetamides, urea derivatives, neonicotinoids, carbamates, triazoles, dithiocarbamates, imidazoles...

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Veröffentlicht in:Journal of analytical chemistry (New York, N.Y.) N.Y.), 2012-11, Vol.67 (11), p.904-924
Hauptverfasser: Amelin, V. G., Bol’shakov, D. S., Tretyakov, A. V.
Format: Artikel
Sprache:eng
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Zusammenfassung:s The optimal conditions for the separation and quantification of pesticides of the following classes by capillary electrophoresis are found: aryloxy carboxylic acids, sym -triazines, triazinones, chloroacetamides, urea derivatives, neonicotinoids, carbamates, triazoles, dithiocarbamates, imidazoles, benzimidazoles, and organophosphorus compounds. Procedures are proposed for the determination of pesticides in surface, well, and drinking water after their preconcentration by solid-phase extraction on preconcentration cartridges Oasis® HLB 3cc/60 mg. The recovery of pesticides was 80–95%. The lower limits of the analytical range for pesticides in water with preconcentration was 0.2–1 μg/L; the relative standard deviation did not exceed 10%.
ISSN:1061-9348
1608-3199
DOI:10.1134/S106193481209002X