Catalytic oxidation of hydrocarbons of natural and oil gas

Alkane oxidation by O 2 and CO in the presence of Rh-, Pd-, and Pt-containing catalytic systems leads to the product of C-H bond oxidation and the products of C-C bond oxidative destruction. A deuterated methyl group in acetic acid is observed in the oxidation of n -propane in a deuterium-donor medi...

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Veröffentlicht in:	Petroleum chemistry 2010-09, Vol.50 (5), p.332-337
Hauptverfasser:	Chepaikin, E. G., Bezruchenko, A. P., Menchikova, G. N., Moiseeva, N. I., Gekhman, A. E.
Format:	Artikel
Sprache:	eng
Schlagworte:	2009 Acetic acid Catalysis Chemical properties Chemistry Chemistry and Materials Science Industrial Chemistry/Chemical Engineering Organic acids Oxidation-reduction reaction Palladium The Conference on Actual Problems of Petroleum Zvenigorod
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Beschreibung
Zusammenfassung:	Alkane oxidation by O 2 and CO in the presence of Rh-, Pd-, and Pt-containing catalytic systems leads to the product of C-H bond oxidation and the products of C-C bond oxidative destruction. A deuterated methyl group in acetic acid is observed in the oxidation of n -propane in a deuterium-donor medium. The possible mechanisms of alkane C 2 -C 4 conversion are proposed.
ISSN:	0965-5441 1555-6239
DOI:	10.1134/S0965544110050026