Oxidative functionalization of methane in the presence of a homogeneous rhodium-copper-chloride catalytic system: Transformation of acetic and propionic acids as solvent components

Oxidative functionalization of methane in the presence of a homogeneous rhodium-copper-chloride catalytic system: Transformation of acetic and propionic acids as solvent components

The oxidative functionalization of methane (O2, CO, 95°C, Rh III /Cu I , II /Cl − catalytic system) was studied in an aqueous acetic or propionic acid medium. It was shown that oxidative decarbonylation of carboxylic acids takes place along with methanol and methyl carboxylate formation.

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Veröffentlicht in:Petroleum chemistry 2011-03, Vol.51 (2), p.133-142
Hauptverfasser: Chepaikin, E. G., Bezruchenko, A. P., Menchikova, G. N., Moiseeva, N. I., Gekhman, A. E., Moiseev, I. I.
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Chemistry and Materials Science
Copper
Industrial Chemistry/Chemical Engineering
Methane
Organic acids
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Zusammenfassung:The oxidative functionalization of methane (O2, CO, 95°C, Rh III /Cu I , II /Cl − catalytic system) was studied in an aqueous acetic or propionic acid medium. It was shown that oxidative decarbonylation of carboxylic acids takes place along with methanol and methyl carboxylate formation.
ISSN:0965-5441
1555-6239
DOI:10.1134/S0965544111020022