Doxycycline-sensitized solid-phase fluorescence of europium on silica in the presence of surfactants

The effect of the second ligand and surfactant micelles on the solid-phase time-resolved fluorescence of europium sensitized by doxycycline on Silasorb 600 is studied. A procedure of the sorption-luminescence determination of doxycycline using micelles of Triton X-100 nonionic surfactant is develope...

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Veröffentlicht in:Journal of analytical chemistry (New York, N.Y.) N.Y.), 2013-02, Vol.68 (2), p.112-116
Hauptverfasser: Parashchenko, I. I., Smirnova, T. D., Shtykov, S. N., Kochubei, V. I., Zhukova, N. N.
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container_issue 2
container_start_page 112
container_title Journal of analytical chemistry (New York, N.Y.)
container_volume 68
creator Parashchenko, I. I.
Smirnova, T. D.
Shtykov, S. N.
Kochubei, V. I.
Zhukova, N. N.
description The effect of the second ligand and surfactant micelles on the solid-phase time-resolved fluorescence of europium sensitized by doxycycline on Silasorb 600 is studied. A procedure of the sorption-luminescence determination of doxycycline using micelles of Triton X-100 nonionic surfactant is developed; the detection limit is 1.1 × 10 −7 . The analytical range for doxycycline is 3 × 10 −7 to 3 × 10 −5 M. The procedure is tested on a doxycycline pharmaceutical drug; RSD was no worse than 4%.
doi_str_mv 10.1134/S1061934813020123
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subjects Analytical Chemistry
Chemical properties
Chemistry
Chemistry and Materials Science
Composition
Europium
Fluorescence
Identification and classification
Silica
Surface active agents
title Doxycycline-sensitized solid-phase fluorescence of europium on silica in the presence of surfactants
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