Doxycycline-sensitized solid-phase fluorescence of europium on silica in the presence of surfactants
The effect of the second ligand and surfactant micelles on the solid-phase time-resolved fluorescence of europium sensitized by doxycycline on Silasorb 600 is studied. A procedure of the sorption-luminescence determination of doxycycline using micelles of Triton X-100 nonionic surfactant is develope...
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Veröffentlicht in: | Journal of analytical chemistry (New York, N.Y.) N.Y.), 2013-02, Vol.68 (2), p.112-116 |
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container_title | Journal of analytical chemistry (New York, N.Y.) |
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creator | Parashchenko, I. I. Smirnova, T. D. Shtykov, S. N. Kochubei, V. I. Zhukova, N. N. |
description | The effect of the second ligand and surfactant micelles on the solid-phase time-resolved fluorescence of europium sensitized by doxycycline on Silasorb 600 is studied. A procedure of the sorption-luminescence determination of doxycycline using micelles of Triton X-100 nonionic surfactant is developed; the detection limit is 1.1 × 10
−7
. The analytical range for doxycycline is 3 × 10
−7
to 3 × 10
−5
M. The procedure is tested on a doxycycline pharmaceutical drug; RSD was no worse than 4%. |
doi_str_mv | 10.1134/S1061934813020123 |
format | Article |
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−7
. The analytical range for doxycycline is 3 × 10
−7
to 3 × 10
−5
M. The procedure is tested on a doxycycline pharmaceutical drug; RSD was no worse than 4%.</description><identifier>ISSN: 1061-9348</identifier><identifier>EISSN: 1608-3199</identifier><identifier>DOI: 10.1134/S1061934813020123</identifier><language>eng</language><publisher>Dordrecht: SP MAIK Nauka/Interperiodica</publisher><subject>Analytical Chemistry ; Chemical properties ; Chemistry ; Chemistry and Materials Science ; Composition ; Europium ; Fluorescence ; Identification and classification ; Silica ; Surface active agents</subject><ispartof>Journal of analytical chemistry (New York, N.Y.), 2013-02, Vol.68 (2), p.112-116</ispartof><rights>Pleiades Publishing, Ltd. 2013</rights><rights>COPYRIGHT 2013 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c357t-6d49834e473f150d5f2860b4aaf547d89cab730c44c980aa61aa6afaaafee3e3</citedby><cites>FETCH-LOGICAL-c357t-6d49834e473f150d5f2860b4aaf547d89cab730c44c980aa61aa6afaaafee3e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1061934813020123$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1061934813020123$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Parashchenko, I. I.</creatorcontrib><creatorcontrib>Smirnova, T. D.</creatorcontrib><creatorcontrib>Shtykov, S. N.</creatorcontrib><creatorcontrib>Kochubei, V. I.</creatorcontrib><creatorcontrib>Zhukova, N. N.</creatorcontrib><title>Doxycycline-sensitized solid-phase fluorescence of europium on silica in the presence of surfactants</title><title>Journal of analytical chemistry (New York, N.Y.)</title><addtitle>J Anal Chem</addtitle><description>The effect of the second ligand and surfactant micelles on the solid-phase time-resolved fluorescence of europium sensitized by doxycycline on Silasorb 600 is studied. A procedure of the sorption-luminescence determination of doxycycline using micelles of Triton X-100 nonionic surfactant is developed; the detection limit is 1.1 × 10
−7
. The analytical range for doxycycline is 3 × 10
−7
to 3 × 10
−5
M. The procedure is tested on a doxycycline pharmaceutical drug; RSD was no worse than 4%.</description><subject>Analytical Chemistry</subject><subject>Chemical properties</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Composition</subject><subject>Europium</subject><subject>Fluorescence</subject><subject>Identification and classification</subject><subject>Silica</subject><subject>Surface active agents</subject><issn>1061-9348</issn><issn>1608-3199</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNp9kU1LAzEQhhdRUKs_wFvAk4etySbdj6P4DQVBe1-m2cka2U1KZhdaf72R6qFYJAwJ8z7PHDJJciH4VAiprt8Ez0UlVSkkz7jI5EFyInJeplJU1WF8xzj9zo-TU6IPznlVivwkae78eqM3urMOU0JHdrCf2DDynW3S1TsQMtONPiBpdBqZNwzH4Fd27Jl3jGxnNTDr2PCObBWxX4rGYEAP4AY6S44MdITnP_ckWTzcL26f0vnL4_PtzTzVclYMad6oqpQKVSGNmPFmZrIy50sFYGaqaMpKw7KQXCulq5ID5CIWGIg5okQ5SS63Y1vosLbO-CGA7i3p-kZKWagsK6tIpXuoFh0G6LxDY2N7h5_u4eNpsLd6r3C1I0RmwPXQwkhUP7-97rJiy-rgiQKaehVsD2FTC15_L7b-s9joZFuHIutaDPWHH4OLH_uP9AUEq6Se</recordid><startdate>20130201</startdate><enddate>20130201</enddate><creator>Parashchenko, I. I.</creator><creator>Smirnova, T. D.</creator><creator>Shtykov, S. N.</creator><creator>Kochubei, V. I.</creator><creator>Zhukova, N. N.</creator><general>SP MAIK Nauka/Interperiodica</general><general>Springer</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope></search><sort><creationdate>20130201</creationdate><title>Doxycycline-sensitized solid-phase fluorescence of europium on silica in the presence of surfactants</title><author>Parashchenko, I. I. ; Smirnova, T. D. ; Shtykov, S. N. ; Kochubei, V. I. ; Zhukova, N. N.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c357t-6d49834e473f150d5f2860b4aaf547d89cab730c44c980aa61aa6afaaafee3e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Analytical Chemistry</topic><topic>Chemical properties</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Composition</topic><topic>Europium</topic><topic>Fluorescence</topic><topic>Identification and classification</topic><topic>Silica</topic><topic>Surface active agents</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Parashchenko, I. I.</creatorcontrib><creatorcontrib>Smirnova, T. D.</creatorcontrib><creatorcontrib>Shtykov, S. N.</creatorcontrib><creatorcontrib>Kochubei, V. I.</creatorcontrib><creatorcontrib>Zhukova, N. N.</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><jtitle>Journal of analytical chemistry (New York, N.Y.)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Parashchenko, I. I.</au><au>Smirnova, T. D.</au><au>Shtykov, S. N.</au><au>Kochubei, V. I.</au><au>Zhukova, N. N.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Doxycycline-sensitized solid-phase fluorescence of europium on silica in the presence of surfactants</atitle><jtitle>Journal of analytical chemistry (New York, N.Y.)</jtitle><stitle>J Anal Chem</stitle><date>2013-02-01</date><risdate>2013</risdate><volume>68</volume><issue>2</issue><spage>112</spage><epage>116</epage><pages>112-116</pages><issn>1061-9348</issn><eissn>1608-3199</eissn><abstract>The effect of the second ligand and surfactant micelles on the solid-phase time-resolved fluorescence of europium sensitized by doxycycline on Silasorb 600 is studied. A procedure of the sorption-luminescence determination of doxycycline using micelles of Triton X-100 nonionic surfactant is developed; the detection limit is 1.1 × 10
−7
. The analytical range for doxycycline is 3 × 10
−7
to 3 × 10
−5
M. The procedure is tested on a doxycycline pharmaceutical drug; RSD was no worse than 4%.</abstract><cop>Dordrecht</cop><pub>SP MAIK Nauka/Interperiodica</pub><doi>10.1134/S1061934813020123</doi><tpages>5</tpages></addata></record> |
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subjects | Analytical Chemistry Chemical properties Chemistry Chemistry and Materials Science Composition Europium Fluorescence Identification and classification Silica Surface active agents |
title | Doxycycline-sensitized solid-phase fluorescence of europium on silica in the presence of surfactants |
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