Synthesis of @NiO Core-Shell Type Nanostructures and Microextrusion Printing of a Composite Anode Based on Them

The process of the hydrothermal synthesis of hierarchically organized nanomaterials with the core-shell structure with the composition ((CeO[sub.2])[sub.0.8](Sm[sub.2]O[sub.3])[sub.0.2])@NiO was studied, and the prospects for their application in the formation of planar composite structures using microextrusion printing were shown. The hydrothermal synthesis conditions of the (CeO[sub.2])[sub.0.8](Sm[sub.2]O[sub.3])[sub.0.2] nanospheres were determined, and the approach to their surface modification by growing the NiO shell with the formation of core-shell structures equally distributed between the larger nickel(II) oxide nanosheets was developed. The resulting nanopowder was used as a functional ink component in the microextrusion printing of the corresponding composite coating. The microstructure of the powders and the oxide coating was studied by scanning (SEM) and transmission electron microscopy (TEM), the crystal structure was explored by X-ray diffraction analysis (XRD), the set of functional groups in the powders was studied by Fourier-transform infrared spectroscopy (FTIR) spectroscopy, and their thermal behavior in an air flow by synchronous thermal analysis (TGA/DSC). The electronic state of the chemical elements in the resulting coating was studied using X-ray photoelectron spectroscopy (XPS). The surface topography and local electrophysical properties of the composite coating were studied using atomic force microscopy (AFM) and Kelvin probe force microscopy (KPFM). Using impedance spectroscopy, the temperature dependence of the specific electrical conductivity of the obtained composite coating was estimated.