Reactions of Benzylidene Chlorides with 5-Methyl Diethylphosphinothioate

Reactions of Benzylidene Chlorides with 5-Methyl Diethylphosphinothioate

S-Methyl diethylphosphinothioate reacted with benzylidene chlorides to give the corresponding aryl(chloro)methyl methyl sulfide and diethylphosphinoyl chloride. The product structure suggests initial attack of the methylsulfanyl group on the CH carbon atom of dichloromethylarene. Arenecarbothialdehy...

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Veröffentlicht in:Russian journal of general chemistry 2019-12, Vol.89 (12), p.2386
Hauptverfasser: Gazizov, M.B, Valieva, G.D, Ivanova, S.Yu, Karimova, R.F, Khairullin, R.A, Gazizova, K.S
Format: Artikel
Sprache:eng
Schlagworte:
Chlorides
Dichloropropane
Dimethyl sulfide
Esters
Phosphonates
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Zusammenfassung:S-Methyl diethylphosphinothioate reacted with benzylidene chlorides to give the corresponding aryl(chloro)methyl methyl sulfide and diethylphosphinoyl chloride. The product structure suggests initial attack of the methylsulfanyl group on the CH carbon atom of dichloromethylarene. Arenecarbothialdehyde dithioacetals and trimers and O,O-dialkyl[aryl(methylsulfanyl)methyl]phosphonates were synthesized. Keywords: S-methyl diethylphosphinothioate, benzylidene chlorides, [alpha]-chloro sulfide, arenecarbothialdehyde trimers, O,O-dialkyl[aryl(methylsulfanyl)methyl]phosphonates DOI: 10.1134/S1070363219120107
ISSN:1070-3632
DOI:10.1134/S1070363219120107