Spectral Luminescent Properties of 2-Aryl-5- -1H-1,3,4-adiazoles
2-Aryl-5-(2,6-dimethoxyphenyl)-1H-1,3,4-oxadiazoles were synthesized by cyclization reaction of benzoylbenzohydrazides in SOCl2, and their spectral luminescent properties were studied. The oxadiazoles containing phenyl or o-methoxyphenyl substituents in the position 2 were shown to luminesce with a...
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Veröffentlicht in: | Russian journal of general chemistry 2018-02, Vol.88 (2), p.338 |
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Hauptverfasser: | , , , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | 2-Aryl-5-(2,6-dimethoxyphenyl)-1H-1,3,4-oxadiazoles were synthesized by cyclization reaction of benzoylbenzohydrazides in SOCl2, and their spectral luminescent properties were studied. The oxadiazoles containing phenyl or o-methoxyphenyl substituents in the position 2 were shown to luminesce with a high quantum yield in polar and nonpolar solvents. The replacement of these substituents by 2-hydroxyphenyl group led to oxadiazole intensely emitting only in highly polar aprotic DMSO. Keywords: 2,5-diaryl-1,3,4-oxadiazoles, luminescence, luminescence quantum yield, organic phosphors DOI: 10.1134/S107036321802024X |
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ISSN: | 1070-3632 |
DOI: | 10.1134/S107036321802024X |