REFRACTIVE AND ELECTROPHYSICAL PROPERTIES OF DISPERSED SOLUTIONS OF FULLERENE [C.sub.60] IN BINARY SOLVENTS

An experimental study has been made of the influence of the concentration of a solvent and a solute on the clusterization of fullerene [C.sub.60] molecules in a [C.sub.60]/xylol/hexane solution by refractometry methods. By the methods of dynamic light scattering and transmission electron microscopy...

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Veröffentlicht in:Journal of engineering physics and thermophysics 2022-03, Vol.95 (2), p.527
1. Verfasser: Makhmanov, U.K
Format: Artikel
Sprache:eng
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Zusammenfassung:An experimental study has been made of the influence of the concentration of a solvent and a solute on the clusterization of fullerene [C.sub.60] molecules in a [C.sub.60]/xylol/hexane solution by refractometry methods. By the methods of dynamic light scattering and transmission electron microscopy it has been established that when a nonequilibrium method of preparation of a fullerene [C.sub.60] solution in binary mixtures (xylol + hexane) is employed negatively charged clusters of diameters ~ 60-70 nm are formed in the solution. It has been established that the high aggregative stability of the solution of fullerene with a concentration of [C.sub.60] of -0.036 g/L is determined by the relatively high values of the electrokinetic [zeta] potential of nanoclusters ([zeta] = -26.6-28.2 mV).
ISSN:1062-0125
DOI:10.1007/s10891-022-02508-9