Measurement of distribution coefficients on TODGA resin and development of a group separation for mixed activation and fission product samples
Batch equilibrium experiments were performed to determine the distribution coefficients for Sc, Ir, and Ta on N , N , N ′, N ′ tetraoctyl-1,5-diglycolamide (TODGA) resin in various acid matrices. Distribution coefficients were determined in hydrochloric acid (Sc, Ir), nitric acid (Sc, Ta), and a mix...
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Veröffentlicht in: | Journal of radioanalytical and nuclear chemistry 2020-12, Vol.326 (3), p.1669-1678 |
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Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Batch equilibrium experiments were performed to determine the distribution coefficients for Sc, Ir, and Ta on
N
,
N
,
N
′,
N
′ tetraoctyl-1,5-diglycolamide (TODGA) resin in various acid matrices. Distribution coefficients were determined in hydrochloric acid (Sc, Ir), nitric acid (Sc, Ta), and a mixture of nitric acid and 0.2 M hydrofluoric acid (Sc, Ir, Ta). The distribution coefficients determined through these experiments were then utilized to create a group separation method for activation products, fission products, and environmental constituents. |
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ISSN: | 0236-5731 1588-2780 |
DOI: | 10.1007/s10967-020-07460-7 |