Effect of Hydrogen, Carbon Monoxide, Synthesis Gas, and Steam Additives on the Characteristics of Matrix Conversion of Rich Methane–Oxygen Mixtures

An experimental study and detailed kinetic modeling of characteristics of the matrix conversion of a methane–oxygen mixture with the addition of hydrogen, carbon monoxide, synthesis gas, and steam have been carried out. It has been shown that the most significant effect on the product composition is...

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Veröffentlicht in:	Petroleum chemistry 2020-07, Vol.60 (7), p.818-826
Hauptverfasser:	Savchenko, V. I., Nikitin, A. V., Ozerskii, A. V., Zimin, Y. S., Sedov, I. V., Arutyunov, V. S.
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetylene Additives Admixtures Analysis Carbon monoxide Chemistry Chemistry and Materials Science Chemistry, Organic Chemistry, Physical Composition effects Computer simulation Conversion Energy & Fuels Engineering Engineering, Chemical Engineering, Petroleum Hydrogen Industrial Chemistry/Chemical Engineering Methane Physical Sciences Science & Technology Synthesis gas Technology
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Beschreibung
Zusammenfassung:	An experimental study and detailed kinetic modeling of characteristics of the matrix conversion of a methane–oxygen mixture with the addition of hydrogen, carbon monoxide, synthesis gas, and steam have been carried out. It has been shown that the most significant effect on the product composition is provided by the admixture of steam, which reduces the yield of acetylene and at the same time increases the H 2 /CO ratio. The kinetic simulation results appear to agree well with the experimental data obtained.
ISSN:	0965-5441 1555-6239
DOI:	10.1134/S0965544120070130