The phase diagram of the isobaric binary system (NaNO3 + RbNO3)

The phase diagram of the isobaric binary system (NaNO 3  + RbNO 3 ) was traced from the results obtained by using simultaneous direct and differential thermal analysis, differential scanning calorimeter, and X-ray diffraction. This phase diagram shows seven invariants: two eutectics, one eutectoid,...

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Veröffentlicht in:Journal of thermal analysis and calorimetry 2016-06, Vol.124 (3), p.1145-1151
Hauptverfasser: Karoui, Nesrine Ksiksi, Hellali, Dalila, Saidi, Akram, Zamali, Hmida
Format: Artikel
Sprache:eng
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Zusammenfassung:The phase diagram of the isobaric binary system (NaNO 3  + RbNO 3 ) was traced from the results obtained by using simultaneous direct and differential thermal analysis, differential scanning calorimeter, and X-ray diffraction. This phase diagram shows seven invariants: two eutectics, one eutectoid, one peritectic, and three metatectics at (447, 449, 433, 561, 473, 496, and 581) ± 1 K, respectively. A congruently melting intermediate compound, NaRb 2 (NO 3 ) 3 , was also observed. It melts at (451 ± 1) K and has two polymorphic transitions at (437 ± 1) and (443 ± 1) K.
ISSN:1388-6150
1588-2926
DOI:10.1007/s10973-015-5226-4