The phase diagram of the isobaric binary system (NaNO3 + RbNO3)
The phase diagram of the isobaric binary system (NaNO 3 + RbNO 3 ) was traced from the results obtained by using simultaneous direct and differential thermal analysis, differential scanning calorimeter, and X-ray diffraction. This phase diagram shows seven invariants: two eutectics, one eutectoid,...
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Veröffentlicht in: | Journal of thermal analysis and calorimetry 2016-06, Vol.124 (3), p.1145-1151 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
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Zusammenfassung: | The phase diagram of the isobaric binary system (NaNO
3
+ RbNO
3
) was traced from the results obtained by using simultaneous direct and differential thermal analysis, differential scanning calorimeter, and X-ray diffraction. This phase diagram shows seven invariants: two eutectics, one eutectoid, one peritectic, and three metatectics at (447, 449, 433, 561, 473, 496, and 581) ± 1 K, respectively. A congruently melting intermediate compound, NaRb
2
(NO
3
)
3
, was also observed. It melts at (451 ± 1) K and has two polymorphic transitions at (437 ± 1) and (443 ± 1) K. |
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ISSN: | 1388-6150 1588-2926 |
DOI: | 10.1007/s10973-015-5226-4 |